49:00
1. Mechanism: How Energies and Kinetic Order Influence Reaction Rates
48:14
2. Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities
46:46
3. Rate and Selectivity in Radical-Chain Reactions
50:08
4. Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions
47:10
5. Solvation, H-Bonding, and Ionophores
46:47
6. Brønsted Acidity and the Generality of Nucleophilic Substitution
51:56
7. Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile
48:27
8. Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon
48:05
9. Pentavalent Carbon? E2, SN1, E1
51:15
10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
52:08
11. Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes
49:05
12. Nucleophilic Participation During Electrophilic Addition to Alkenes
50:55
13. Addition to Form Three-Membered Rings: Carbenoids and Epoxidation
49:39
14. Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis
50:36
15. Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization
46:27
16. Isoprenoids, Rubber, and Tuning Polymer Properties
49:37
17. Alkynes. Conjugation in Allylic Intermediates and Dienes
47:46
18. Linear and Cyclic Conjugation Theory. 4n+2 Aromaticity
49:13
19. Aromatic Transition States: Cycloaddition and Electrocyclic Reactions
49:47
20. Electronic and Vibrational Spectroscopy
53:39
21. Functional Groups and Fingerprints in IR Spectroscopy. Precession of Magnetic Nuclei
49:21
22. Medical MRI and Chemical NMR
48:20
23. Diamagnetic Anisotropy and Spin-Spin Splitting
51:13
24. Higher-Order Effects, Dynamics, and the NMR Time Scale
50:29
25. C-13 and 2D NMR. Electrophilic Aromatic Substitution
50:49
26. Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg
45:34
27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
49:04
28. Mechanism and Equilibrium of Carbonyl Reactions
50:02
29. Imines and Enamines. Oxidation and Reduction
46:58
30. Oxidation States and Mechanisms
46:08
31. Periodate Cleavage, Retrosynthesis, and Green Chemistry
47:33
32. Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison
49:20
33. Green Chemistry. Acids and Acid Derivatives
34. Acids and Acid Derivatives
48:49
35. Acyl Insertions and [gr]α-Reactivity
53:07
36. [gr]α-Reactivity and Condensation Reactions
54:47
37. Proving the Configuration of Glucose and Synthesizing Two Unnatural Products
52:09
38. Review: Synthesis of Cortisone
